Critical Micelle Concentration (CMC):

The critical micelle concentration (CMC) is defined as the concentration of 'surface active molecules' or surfactants above which micelles are spontaneously formed in water.

Surfactants can arrange themselves at the surface of the water such that the one part interacts with the water and the other interacts with the air. However, the presence of these molecules on the surface lowers the surface tension. At low concentrations surfactants will favor arrangement on the surface because as the surface becomes crowded with surfactant more molecules will arrange into micelles. Based on this, measurements of surface tension can be used to determine the CMC.

CMC is an important characteristic of a surfactant. At concentrations below the CMC, surface tension changes dramatically with the concentration of the surfactant. After reaching the CMC, the surface tension becomes more constant.