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We get an overshoot in the velocity profile in the laminar FLUENT solution that is not predicted by classical boundary layer theory. It turns out this is a real effect that is missed by boundary layer theory due to one of the assumptions it makes, namely, that the outer flow is the inviscid flow past a flat plate. This is true if the boundary layer is infinitely thin which is valid only in the limit as Reynolds no. tends to infinity. At a finite Reynolds number, the boundary layer has a thickness which displaces the outer flow and causes the overshoot seen in the FLUENT solution. This is explained in more detail in the following video.

For a closer look at this, you can go to the exercises page here
 

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