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h1. Tapered vs. Uniform Baffle Configuration h3. Abstract The vertical flow hydraulic flocculator has been used to test tapered and uniform baffle configurations during previous semesters, but the two configurations have never been compared with similar raw water conditions. For this reason the Fall 2008 Pilot Plant Flocculation team focused on determining which flocculation configuration is optimal. The tapered flocculation configuration model is based on the G-theta Model, while uniform configuration is based on the energy dissipation model. It has recently been determined that the Gtheta model used to design the tapered flocculator is inaccurate. Gtheta describes mixing in the viscous subrange. Mixing in a turbulent flow hydraulic flocculator is better modeled by energy dissipation rate in the flocculator. The energy dissipation model suggests that the difference in performance between tapered and uniform flocculators might not be that large. The uniform versus tapered flocculator tests were performed to confirm this theory. In our final results, the tapered baffle configuration produced marginally better turbidity than the uniform baffle configuration. However, due to low temperature conditions, the incoming turbidity was too low in order to produce conclusive results. h3. Introduction and Objectives Recently development in Aguaclara technology have shown that the Gtheta model may be inappropriate to describe flocculation. A main goal of the pilot plant flocculation team was to determine the optimal flocculation configuration: Tapered or Uniform Baffle Spacing. Using the Gtheta model a tapered configuration would expose flocs to high shear initially and as flocs grew they would be exposed to less shear. Using an energy dissipation model, the uniform configuration would be optimal. The Pilot Plant flocculation team approached this problem by first determining the optimal spacing for the tapered flocculation configuration. It was then determined that the two configurations would only be comparable if the uniform spacing was equal to the last section of the tapered spacing. The tapered and uniform spacings were compared consecutively. The tests were then run in the same day to ensure similar environmental conditions and comparable data. An important aspect of the vertical flow hydraulic flocculator is the alum dosing One of the main issues of this semester was determining appropriate alum dosing in the cold. This problem was approached by inquiring the staff at the Water Filtration Plant about their Polyaluminum Chloride dosing. Their dosage was then converted so that the Pilot Plant can insure proper dosage with a simple equation based on the plant's dosage. h1. Sampling Method h5. Overview This sampling method in the flocculator at the Pilot Plant has been used for several semester's research. Alum is used as a coagulant and the dose can be set using process controller. Raw water running through flocculation tank can be sampled at any desired location. Sampling lines run to turbidimeters from three mobile tube settlers. The tube settlers mimic sedimentation. Additionally a sampling line runs from the raw water inlet to a turbidimeter. Turbidity data is stored in a excel spreadsheet using process controller. h5. [Alum Dosing| PP AD] Because the pilot plant takes water directly from the stream, environmental conditions change all the time and affect the incoming turbidity to the plant as well as the chemical composition of the particles causing turbidity. It is incredibly important to determine the best alum dose for each day of testing to ensure the formation of good flocs and collect appropriate data. The alum dose can also be related to the plant's PAC dosage using the relationship 1 part per million is equivalent to 0.182 mg/L. h5. [Tube Settlers| PP TubeSet] Tube Settlers are used to mimic sedimentation before the turbidity of water in the flocculator is measured. They can be moved to different locations along the flocculator in order to examine effluent turbidity at various stages of flocculation. h5. [Data Collection and Analysis| PP Data] Data is collected using [process controller| On opening PC]. It is stored in [processexcel controller| On opening PC] spreadsheets and then analyzed. h1. Results The team had difficulty finding the correct alum dose at low temperatures and incoming turbidity this semester. The team determined a relationship between the Water Filtration Plant's PAC (polyaluminum chloride) dosage and the alum dose at the plant. PAC is the coagulant that is used by the WFP. The composition and molecular weight of PAC is a trade secret and its chemical formula is unknown. According to the WFP operators, at the plant 48.8% of 11.1 lb/gal of the alum stock concentration is active and 33% of 10.84 lb/gal of PAC stock concentration is active. The relationship was determined between the percent active ingredients in PAC and alum. Therefore 1 ppm of PAC should have the same effects on flocculation as 0.182 mg/L alum. However, it must be noted that this relationship is not based on the molecular weights of aluminum present in both alum and PAC. Due to PAC's composition being a trade secret, it is impossible to determine and equivalent ratio between alum and PAC based on the aluminum composition within each compound. The ratio was calculated based on active concentrations for both stock solutions. Note that the experiments were conducted in low temperatures and low incoming turbidities. The temperature of the environment during the experiments was \-3°C. \\ h6. Figure 1: Effluent Turbidity vs. Alum Dosage. (12/14/08) {float:left} !Alum.JPG|width=500! {float} \\ Once this relationship was determined, it was used to set the flocculation tank dosage. The resulting dosage was much lower than expected. At average incoming turbidity of 2.3 NTU it was determined that the optimal alum dose would be around 4 mg/L (Figure 1). As can be seen in the figure below this alum dose gave the best effluent quality, although the differences in NTU between 4 mg/L and 9 mg/L are very slight. The configuration of the uniform and tapered flocculator was changed to agree with the energy dissipation model of flocculation. Previously the end of the tapered flocculator the baffle spacing was 15 cm, this resulted in a energy dissipation lower than the recommended value of 0.4 mW/kg. In order to achieve the recommended value of energy dissipation the spacing in the flocculator was changed to 13.2 cm. This value was calculated using the equation: {include:epsiloncell} The spacing of the uniform flocculator was altered to match the last section of the tapered flocculator so that floc break up would not occur due to shear in the uniform flocculator. The resulting energy dissipation values for the tube flocculator are given a flow rate of 100 L/min: || Section || Spacing ||Number of Baffles || Energy Dissipation mW/kg || | 1 | 3.339 | 2| 98.657 | | 2 | 3.9529 | 4 | 50.2683 | | 3 | 5.7948 | 5 | 10.889 | | 4 | 10.0711 | 11 |1.1922 | | 5 | 13.2322| 11 | 0.4 | A turbidity profile for the uniform and tapered flocculator was determined using this alum dose. The results are inconclusive\- neither configuration produced an effluent with a lower turbidity than the raw water entering the flocculator. Furthermore in the graph shown below the flow rate was decreased to 13.6 gal/min producing an energy gradient of only 0.055 mW/kg throughout the uniform flocculator (Figure 2). h6. Figure 2: Uniform vs. Tapered Configuration. (12/14/08) {float:left|border=2px solid black} !Turbidityprof.jpg|width=500! {float} \\ h1. Conclusions The alum dose set based on plant PAC dosage gave the best results for an incoming turbidity of 2.3 NTU. If this relationship is confirmed to work at a broad range of incoming turbidities, it can hopefully be used by future semesters. The plant operators obviously have much more experience determining alum dosing and this relationship can help us take advantage of their expertise. The turbidity profiles along the flocculator show little difference between the uniform and tapered configuration. Neither configuration shows a better effluent turbidty than the raw water turbidity. The tapered flocculator performed slightly better than the uniform flocculator, this is to be expected as more reasonable energy gradients were occuring in the tapered flocculator. Although the energy gradients are extremely low, clearly flocculation is occuring as seen by the initial increase in turbidity. This increase shows that flocs too small to settle out but large enough to increase the turbidity of the flocculator were forming. In addition, these flocs began to increase in size and number and proceeded to settle out. |
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